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IX
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| § 50. | VirialThe "Virial" is a quantity related to the average kinetic energy of a system, used here to calculate gas pressure. of the external pressure acting on a gas . . . . | 142 |
| § 51. | Probability of the occurrence of pairs of molecules with a given central distance . . . . . . . . . . . . | 143 |
| § 52. | Virial resulting from the finite size of the molecules | 149 |
| § 53. | Virial of the van der Waals cohesive forces . . . . . . . . | 151 |
| § 54. | Alternative formulas for the van der Waals equation . . . . . . . | 153 |
| § 55. | Virial for an arbitrary law of molecular repulsion . | 155 |
| § 56. | The principle of the Lorentz method . . . . . . . . | 157 |
| § 57. | Number of collisions . . . . . . . . . . . . . . | 161 |
| § 58. | More precise value of the mean free path. Calculation of $W_i'$ according to Lorentz's method . . . . . . . . . . . . . . | 164 |
| § 59. | More precise calculation of the space available for the center of a molecule . . . . . . . . . . . . . . . | 165 |
| § 60. | Calculation of saturated vapor pressure from probability theorems . . . . . . . . . . . . . | 167 |
| § 61. | Calculation of the entropyA measure of a system's thermal energy per unit temperature that is unavailable for doing useful work, often interpreted as "disorder." of a gas fulfilling van der Waals' assumptions according to the calculus of probability . . . . . . . . . . . . . . . . . . . . | 171 |
Section VI.
Theory of Dissociation . . . . . . . . . . . . . . . . . . . . . . . 177
| § 62. | Mechanical image of the chemical affinity of monovalent atoms of the same kind . . . . . . . . . . . . . . . . | 177 |
| § 63. | Probability of the chemical bonding of an atom with one of the same kind . . . . . . . . . . . . . . . | 180 |
| § 64. | Dependence of the degree of dissociation on pressure . . . . | 185 |
| § 65. | Dependence of the degree of dissociation on temperature . | 188 |
| § 66. | Numerical calculations . . . . . . . . . . . . . . | 192 |
| § 67. | Mechanical image of the affinity of two different monovalent atoms . . . . . . . . . . . . . . . . . . | 196 |
| § 68. | Dissociation of a molecule into two heterogeneous atoms . . | 200 |
| § 69. | Dissociation of hydrogen chloride gas . . . . . . . . | 202 |
| § 70. | Dissociation of water vapor . . . . . . . . . . . | 203 |
| § 71. | General theory of dissociation . . . . . . . . . | 206 |
| § 72. | Relationship of this theory to the theory of Gibbs . | 211 |
| § 73. | The sensitive region is uniformly distributed around the entire atom . . . . . . . . . . . . . . . . | 213 |
Section VII.
Supplements to the theorems on thermal equilibrium in gases with complex molecules . . . . . . . . . . . . . 217
| § 74. | Definition of the quantity $H$, which measures the probability of a state . . . . . . . . . . . . . . . . . . . | 217 |
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